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News
PENTAERYTHRITL MSDS
2016/7/29      Read:256

MATERIAL SAFETY DATA SHEET
PENTAERYTHRITOL
 
 
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
 
MSDS Name: PENTAERYTHRITOL
Synonyms:
     Tetrakis(hydroxymethyl)methane;
     2,2-Bis-(hydroxymethyl)-1,3-propanediol.
 
Company :SHANGHAI BESTSUNSHINE INTERNATIONAL CO.,LTD
Address: Room 404  Building 20,Mantingfang Garden, No.722 ,Zi zhu Rd.,.Kunshan City ,Jiangsu Province,China,Zipcode:215316
Tel:+86-512-57734349 
Emergency call:+8613584887001
 
SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS No                      Chemical Name                Index 
115-77-5                   PENTAERYTHRITOL                95%--99.5%
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
 
SECTION 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Hygroscopic (absorbs moisture from the air).Moisture sensitive.
Potential Health Effects
     Eye:May cause eye irritation.
     Skin:May cause skin irritation. May be harmful if absorbed through the skin.
     Ingestion:May cause irritation of the digestive tract. Expected to be a low ingestion hazard. May be harmful if swallowed.
     Inhalation:May cause respiratory tract irritation. May be harmful if inhaled.
     Chronic:Not available.
 
SECTION 4 - FIRST AID MEASURES
     Eyes:
          Do NOT allow victim to rub eyes or keep eyes closed. Gently lift
          eyelids and flush continuously with water.
     Skin:
          Flush skin with plenty of water for at least 15 minutes while
          removing contaminated clothing and shoes.
     Ingestion:
          Never give anything by mouth to an unconscious person. Call a poison
          control center. Wash mouth out with water.
     Inhalation:
          Remove from exposure and move to fresh air immediately.
     Notes to Physician:
 
SECTION 5 - FIRE FIGHTING MEASURES
  General Information:
          As in any fire, wear a self-contained breathing apparatus in
          pressure-demand, MSHA/NIOSH (approved or equivalent), and full
          protective gear. This material in sufficient quantity and reduced
          particle size is capable of creating a dust explosion.
     Extinguishing Media:
          Use water spray, dry chemical, carbon dioxide, or chemical foam.
 
SECTION 6 - ACCIDENTAL RELEASE MEASURES
     General Information: Use proper personal protective equipment as indicated  in Section 8.
     Spills/Leaks:
          Scoop up with a nonsparking tool, then place into a suitable
          container for disposal. Provide ventilation.
 
 SECTION 7 - HANDLING and STORAGE 
     Handling:Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
     Storage:Store in a cool, dry place. Store in a tightly closed container.
 
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
     Engineering Controls:
          Facilities storing or utilizing this material should be equipped
          with an eyewash facility and a safety shower.
     Personal Protective Equipment
             Eyes:Wear chemical goggles.
             Skin:Wear appropriate protective clothing to prevent skin exposure.
             Clothing:Wear a chemical apron.
             Respirators:A NIOSH/MSHA approved air purifying dust or mistrespirator or European Standard EN 149.
 
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

Form: Crystalline

Colour: White

Odour: Odourless

Change in condition

Melting point/Melting range: Undetermined.

Boiling point/Boiling range: > 276°C

Flash point: 150°C

Ignition temperature: 390°C

Self-igniting: Product is not selfigniting.

Danger of explosion: Product is not explosive. However, formation of explosive

air-vapour/dust mixtures are possible.

Vapour pressure at 20°C: < 0.001 Pa

Density at 20°C: 0.8 g/cm³

Solubility in / Miscibility with water at 20°C: 50 g/l

pH-value at 20°C: 4-7

Partition coefficient (n-octanol/water): - 1.7 log POW

Thermal decomposition / conditions to be avoided:

No decomposition if used according to specifications.
 
SECTION 10 - STABILITY AND REACTIVITY
     Chemical Stability:
          Stable under normal temperatures and pressures.
     Conditions to Avoid:
          Incompatible materials, excess heat.
     Incompatibilities with Other Materials:
          Strong oxidizing agents, strong acids, acid chlorides, acid
          anhydrides.
     Hazardous Decomposition Products:
          Carbon monoxide, carbon dioxide.
     Hazardous Polymerization: Will not occur.
 
 
 
SECTION 11 - TOXICOLOGICAL INFORMATION 
     RTECS#:
          CAS# 115-77-5: RZ2490000
     Carcinogenicity:
       PENTAERYTHRITOL -
          Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
     Other:
          See actual entry in RTECS for complete information.
 
SECTION 12 - ECOLOGICAL INFORMATION

LD/LC50 values relevant for classification:

115-77-5 pentaerythritol

Oral LD0 > 5110 mg/kg (rat)

LD50 25 500 mg/kg (rat)

Inhalative LC50/4 h NOEL > 11 mg/l (rat)

Primary irritant effect:

on the skin: No irritating effect.

on the eye: No irritating effect.

Sensitization: No sensitizing effects known.

Other information (about experimental toxicology):

 Ames test: Negative (Not a mutagen)

Additional toxicological information: Mutagenicity (Ames test): Negative

#Information about elimination (persistence and degradability):

115-77-5 pentaerythritol

BOD28 0.99 g/g (OECD 301)

COD 1380 mg/g

TOD 1300 mg/g

Behaviour in environmental systems:

Mobility and bioaccumulation potential:

Due to the distribution coefficient n-octanol/water an accumulation in organisms is not expected.

Ecotoxicological effects:

Remark: Harmless to fish up to the tested concentration

General notes:

Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water

Do not allow undiluted product or large quantities of it to reach ground water, water course or

sewage system.

European waste catalogue

07 00 00 WASTES FROM ORGANIC CHEMICAL PROCESSES

(Contd. on page 4)

07 01 00 wastes from the manufacture, formulation, supply and use (MFSU) of basic organic chemicals

07 01 99 wastes not otherwise specified

Recommendation: Disposal must be made according to official regulations.

Land transport ADR/RID (cross-border)

ADR/RID class: -

Remarks: Not controlled under ADR/RID, IMDG or IATA.

Maritime transport IMDG:

IMDG Class: -

Remarks: Not controlled under IMDG.

Air transport ICAO-TI and IATA-DGR:

ICAO/IATA Class: -

Remarks: Not controlled under IATA.

Special labelling of certain preparations:

Safety data sheet available for professional user on request.

Waterhazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.

This Safety Data Sheet is not a Product Specification. It is based on our present knowledge and

experience and it is intended to serve as a guide for safe handling of the product regarding to

health and environmental aspects.

SECTION 13 - DISPOSAL CONSIDERATIONS
 
Dispose of in a manner consistent with federal, state, and local regulations.
 
                  SECTION 14 - TRANSPORT INFORMATION
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
 
SECTION 15 - REGULATORY INFORMATION 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25  Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 115-77-5: 1
United Kingdom Occupational Exposure Limits
AS# 115-77-5: OES-United Kingdom, TWA 10 mg/m3 TWA (total inhalable dust); 4 mg/m3 TWA (respirable dust)
CAS# 115-77-5: OES-United Kingdom, STEL 20 mg/m3 STEL (total inhalable dust)
Canada
CAS# 115-77-5 is listed on Canada's DSL List.
CAS# 115-77-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 115-77-5: OEL-AUSTRALIA:TWA 10 mg/m3
          OEL-BELGIUM:TWA 10 mg/m3
          OEL-FINLAND:TWA 10 mg/m3;STEL 20 mg/m3
          OEL-FRANCE:TWA 10 mg/m3
          OEL-THE NETHERLANDS:TWA 10 mg/m3
          OEL-UNITED KINGDOM:TWA 10 mg/m3;STEL 20 mg/m3 (total dust)
          OEL-UNITED KINGDOM:TWA 5 mg/m3 (resp. dust)
          OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
          OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
 US FEDERAL
TSCA
CAS# 115-77-5 is listed on the TSCA inventory.
 
SECTION 16 - ADDITIONAL INFORMATION
     MSDS Creation Date:  01/01/2000  Revision #0 Date: 01/01/2005.
 
     The information above is believed from reliable resource to be accurate and represents the stinformation currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability sulting from its use. Users should make their own investigations to determine the suitability of heinformation or heir particular purposes. In no way shall the company be liable for any claims, losses, r damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary amages, however arising, even if the company has been advised of the possibility of such damages.

 

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Address: No.722 ,Zi zhu Rd.,Kunshan City
Jiangsu Province,China,Zipcode:215316 
  
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